R-12 belongs to which family of refrigerants?

R-12 is a CFC. It is the same refrigerant as CFC-12, a chlorofluorocarbon made of chlorine, fluorine and carbon, with no hydrogen.

  • CFCCorrect answer
  • HFC
  • HCFC
  • HFO

Why “CFC” is correct

R-12 is a chlorofluorocarbon (CFC): it contains chlorine, fluorine and carbon and no hydrogen. CFCs such as R-11 and R-12 have the highest ozone depletion potential of the common refrigerants.

Source: EPA: Test Topics

Why the other answers are wrong

  • HFC — HFCs such as R-134a replaced R-12; they contain no chlorine.
  • HCFC — R-22 is the classic HCFC; R-12 has no hydrogen in it.
  • HFO — HFOs are newer low-GWP substitutes, not the older refrigerant R-12.

The source, word for word

not chemical formulas, but idea that R-12 is a CFC, R-22 is an HCFC, R-134 is an HFC, etc.
EPA: Section 608 Test Topics
A compound consisting of chlorine, fluorine, and carbon.
EPA: Section 608 Test Topics

Common refrigerants by family

EPA's outline says you need to know which family a refrigerant belongs to, not its chemical formula.

Examples from EPA's Section 608 test topics and reference table
FamilyExamplesContains chlorine
CFCR-11, R-12Yes
HCFCR-22Yes
HFCR-134aNo
HFOR-1234yfNo

Why the family matters

The family tells you about ozone: CFCs have the highest ozone depletion potential, then HCFCs, and HFCs have none. It does not tell you whether you can vent, because all three must be recovered.

Keep practicing

Answer checked against EPA: Section 608 Test Topics on .

Unofficial, not affiliated with the EPA or any EPA-approved certifying organization. Questions are original practice written from public EPA material, not real exam questions.